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| Realkalisation |
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Realkalization
can be described as the equivalent of ECE for corroding
steel in carbonated concrete structures. It is a shorter
term treatment (days instead of weeks), and the proprietary
system uses a calcium carbonate electrolyte as an aid
to regenerating the alkalinity in the concrete and around
the rebar. The same anode systems are used as for ECE.
The treatment is most commonly applied to buildings
with carbonation damage but with at least moderate cover
of the reinforcing steel (greater than about 10mm.).
The literature is still contradictory about the use
of the calcium carbonate electrolyte to maintain alkalinity
after treatment and the extent to which it migrates
into the concrete. The pH of calcium carbonate is not
far above the pH corrosion threshold for steel in concrete.
The use of phenolphthalein indicator causes some concern
as its colour change at pH 9.5 is below the corrosion
threshold for steel in concrete at pH 11.
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